Irreversibility and the foehn wind effect


The foehn wind effect describes the phenomeneon, that air, which is crossing a high mountain, after the passage has a higher temperature than before. A necessary requirement is here, that the crossing air lose humidity on the front side, for example by raining.


Fhoen


To understand this phenomeneon, it is important to know, that in the air not all molecules/atoms have the same energy/speed. Some have under average and some have over average energy.
When water molecules unite in a water drop, it is necessary, that they have a relative low amount of energy to hold together. So it can be asumed, although without measuring, that this molecules have under average energy. But if under average individuals leave a system, it is logical, that the remaining rest has a higher level then before.
Foehntropfen
The new created water drop can not be in an equilibrium with the gas atmosphere. A higher material density lead to a higher energy density and so the probability of energy lost is higher than the opposite process. The equilibrium is reached, when the drop has lost enought energy to the gas, which is called condensation heat.

But what has this to do with the concept of irreveribility ? When growing water drops reach a critical mass, they fall down to the earth. But the down fall is an irreversible process, possible only from up to down. Would the water drops remain in the air and pass the mountain, they would vaporize at the back site and no foehn wind effect would appear.

next : Irreversibility and the freezing point depression by addition of salt